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In step 1, the 14C excess 14 is only corrected for isotopic mass fractionation. By themselves, the 13C values represent data that are highly influenced by fractionation in NaOH in the absorbing dish. For additional information on the high-altitude sampling, see Hagemann et al. For additional information on the sampling sites, radiocarbon standards, and carbon isotope measurements, see Nydal , , Craig , and Levin et al. Fortunately it was also recognized that the radioactive isotopes already injected into the atmosphere could be useful tracers in geophysical research. These 14C measurements document the time lag of isotopic sea-air exchange and chronicle a long-term decline in 14CO2 at Northern and Southern hemisphere sites. These measurements complement other radiocarbon data sets Broecker and Olson ; Levin et al. This data set is unique for its inclusion of measurements in the early s that trace the bomb 14C released by a series of nuclear tests. All measurements at the global network of sites were taken by dynamic quantitative absorption of CO2 in NaOH solution. This consistency in sampling technique over a period of three decades is valuable to researchers and modelers.

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